CFD Simulation of Deep-Bed Paddy Drying Process and Performance

Computational Fluid Dynamics (CFD) was applied three-dimensionally to simulate the drying behavior of paddy in a deep-bed dryer. The commercial CFD software Fluent 6.3.26 was used. The deep-bed paddy drying process and performance were studied by incorporating user-defined function (UDF) in Fluent written in C language. The predicted drying parameters were compared with experimental data of deep-bed drying of paddy. The values of mean relative deviation (MRD), standard error of prediction (SEP), and maximum error of prediction (MEP) for prediction of grain moisture content, air temperature, and absolute humidity were less than 6, 10, and 9%; 0.33% (d.b), 1.24°C, and 0.06% (kg/kg of dry air); and 2.25% (d.b), 6.8°C, and 0.37% (kg/kg of dry air), respectively, which reflect reasonable accuracy. Moreover, the energetic and exergetic performance of deep-bed paddy drying were simulated and analyzed. The effects of inlet air temperature and mass flow rate on the performance parameters were investigated. It was shown that the application of higher levels of inlet air temperature and lower mass flow rates yielded higher exergy efficiencies of deep-bed paddy drying.     

Direct synthesis of bi-modal porous structure MCM-41 and its application in CO2 capturing through amine-grafting

A bi-modal porous structure MCM-41 (BPS-MCM-41) was synthesized and functionalized by 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane (TRI); also, its performance in amine grafting and CO₂ capturing was compared with that of pore-expanded MCM-41 [1]. To create larger pores beside the mesoporous structure of MCM-41, carbon black nanoparticles were used as the solid template. Characterizing the BPS-MCM-41 using the BET and BJH techniques resulted in the surface reduction of 29.3 percent and volume increase of 68.46 percent. The pore size distribution showed two peaks: a narrow peak at 2.24 nm diameter, which belonged to micelles, and a wide one at about 50 nm due to the presence of used nanoparticles. The functionalization confirmed that BPS-MCM-41 is capable of accommodating a large quantity of amine groups. The CO₂ adsorption measurement indicated that internal volume of the adsorbent was a critical factor affecting the adsorption capacity of the amine grafted adsorbents.     

Statistical analysis and optimization of simultaneous biological nutrients removal process in an intermittently aerated SBR

Simultaneous removal of carbon and nutrients from a synthetic wastewater in aerobic/anoxic sequence batch reactor (SBR) was investigated. The experiments were conducted based on a central composite design (CCD) and analyzed using response surface methodology (RSM). Two significant independent variables, cycle time and aeration time, were studied to analyze the process. Five dependent parameters—total COD (TCOD) removal, total nitrogen removal, total phosphorus removal, total Kjeldahl nitrogen removal and effluent nitrate concentration—were monitored as the process responses. The region of exploration for the process was taken as the area enclosed by cycle times (2, 4.25 and 6.5 h) and aeration times (30, 40 and 50 min/h) boundaries. The maximum COD (87.18%) and TKN (78.94%) removal efficiencies were obtained at the cycle time and aeration time of 6.5 h and 50 min/h, respectively. While the maximum TN (71.15%) and phosphorus (68.91%) removal efficiencies were obtained at cycle time of 6.5 h and aeration time of 40min/h. As a result, high cycle time (6.5 h) and moderate aeration time (40min/h) were found to be the optimal region for maximum carbon and nitrogen removal efficiencies.     

Preparation and characterization of novel derivatives of chitosan and trimethyl chitosan conjugated with dipeptides and vitamin B12 as candidates for oral delivery of insulin

Chitosan and its derivatives are widely used in drug delivery systems due to their bio-degradebility, bio-compatibility and absorption enhancing properties. Many peptide and protein derived therapeutics cannot be administered through oral rout because of the proteolytic condition of gastro-intestinal tract and their low bio-availability. Insulin is a peptide drug which is widely used in diabetics as repeated daily injection. Due to the fact that there are receptors for didpeptides and vitamine B12 in small intestine, in this research work novel derivatives of chitosan and trimethyl chitosan conjugated with glycyl-glycine, alanyl-alaninie and vitamine B12 were synthesized and characterized. The structure of conjugates as well as substitution of different functional groups was confirmed by different instrumental analytical methods such as Fourier transform infrared, magnetic resonance, and X-ray diffraction spectroscopy. Nano-particles of aforementioned loaded with insulin were prepared and their size, surface electrical charge and morphology characterized and their release profile were studied. The results are promising and reveal that these new chitosan and trimethyl chitosan derivatives are potential vehicles for protein and peptide drug molecules.     

The conditional mean spectra by disaggregating the eta spectral shape indicator

Conditional spectra are a recent development in this field, which utilizes the advantages of spectral shape indicators, for example, epsilon and eta. The application of an eta indicator in conditional spectra calculations depends mainly on calculating the peak ground velocity epsilon, data about which are not readily available in the current literature. This issue has been solved by linear regression between the conventional epsilon and the peak ground velocity epsilon. However, not enough attention has been paid in the literature to the disaggregation of the eta indicator. For this reason, the disaggregation of seismic hazard based on the use of an eta indicator has been investigated in this paper, based on a simplified linear seismic source. The obtained results were compared with the available approach in the literature, which shows that this refinement has a meaningful effect on the conditional spectra specifically in the short period range. Furthermore, eta‐based conditional spectra are used at different hazard levels to select ground‐motion records. A three‐storeyed building is then analysed, and the corresponding annual probability of failure is calculated based on the full dataset as well as on the records, which were selected based on conditional spectra.     

Geometrical and structural setting of landslide dams of the Central Alborz: a link between earthquakes and landslide damming

Bulletin of Engineering Geology and the Environment - The combination of remote sensing observations, geological field investigations and geomorphological mapping and measurements along with faults...     

Dynamic sub-grid scale turbulent Schmidt number approach in large eddy simulation of dispersion around an isolated cubical building

In this paper, the effects of the sub-grid scale (SGS) turbulent Schmidt number, Sc _SGS, on the large eddy simulation of dispersion on and around an isolated cubical model building with a flush vent located on its roof are examined. Constant and dynamic Sc _SGS approaches for SGS turbulent mass flux modeling are employed. Simulation results are compared with the available wind tunnel measurements. Furthermore, the influence of the grid resolution on the accuracy of results predicted by the dynamic Sc _SGS approach is investigated. Detailed statistical analysis of Sc _SGS demonstrates that the dynamically computed Sc _SGS at different locations varies by a factor of almost 5 and a considerable deviation of Sc _SGS from its common values of 0.5 and 0.7 occurs. Particularly, in the vicinity of the building where the concentration gradients are noticeable, Sc _SGS has a larger variation. Also, the probability of occurrence of 0.2 < Sc _SGS <1.5 is more than 90 percent and the Sc _SGS mean values are nearly around 0.8 to 1 with a maximum variance of 0.2. In addition, by refining the grid, the differences between the predictions of constant and dynamic Sc _SGS approaches decrease. This is due to the reduction of sub-grid scales contribution to turbulent dispersion. It is confirmed that dynamic Sc _SGS approach is a practical alternative to the constant Sc _SGS approach, effectively eliminating a user-defined model coefficient.     

Synergistic effect of salt ions and water-soluble amphiphilic compounds of acidic crude oil on surface and interfacial tension

This study investigated the effect of solubility of amphiphilic compounds of acidic crude oil in water on the surface and interfacial tension (IFT) with NaCl, MgCl₂, CaCl₂, and Na₂SO₄ salts. Accordingly, distilled water, along with the salts mentioned in zero ionic strength up to 2 mol were put in contact with crude oil to become saturated with amphiphilic compounds. The effects of these compounds were investigated on the properties of contact water by pH, total organic carbon (TOC), FTIR (Fourier transform infrared spectroscopy), water-air surface tension (ST), and water-n-decane IFT tests. The results showed that some of the organic components of crude oil, especially acidic and basic compounds, are present or soluble in water, which have a significant effect on reducing the surface and IFT. The IFT reduction of water-n-decane was greater than the water-air ST system. Also, the observations showed that for both NaCl and Na₂SO₄ salt water, with increasing ionic strength of water, there was an optimum salinity within the range of 0.1-0.25 mol/L for both salts with the amount of surface and IFT minimized at this point. In the other two salts, this point was delayed upon elevation of ionic strength and was observed at high salinity. In this case, divalent cations reduce tension rate compared to monovalent cations. Due to solubility of acidic and basic groups in water, pH of salt water illustrates an acidic trend. Results of the FTIR test confirmed solubility of these compounds as well.